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nanoporous trinuclear copper pyrazolate-based metal-organic framework

Based on

1 Articles
2017 Most recent source

Composition

1

mixture of substance based on (4-pyrazolecarboxylic acid dianion/4-pyrazolecarboxylic acid dianion/zinc-oxygen cluster/zinc-oxygen cluster/copper(I) cation/copper(I) cation/zinc(II) cation/zinc(II) cation/hydroxyl group/hydroxyl group/water/water)

Type Complex Compound
Formula
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
density

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Catalytic properties

Reaction Value Nanomaterial Variant Source
3,4,5-trimethoxybenzyl alcohol (TMBA) oxidation

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Applications

Area Application Nanomaterial Variant Source
catalysis

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Characterization

Method Nanomaterial Variant Source
diffuse reflectance infrared spectroscopy

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • zinc nitrate hexahydrate
  • copper(II) nitrate trihydrate
  • 4-pyrazolecarboxylic acid
  1. saE7O6HO98TzQE5MfA53p1U1fhvL7LF06ZbJ1SlPmYynpcCojA6LQ
Product

nanoporous trinuclear copper pyrazolate-based metal-organic framework

Pore width: ~ 1 - 3.5 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • zinc nitrate hexahydrate
  • copper(II) nitrate trihydrate
  • 4-pyrazolecarboxylic acid
  1. PUg4P4Jn49TEUsvzSzv20b9F7tjAyGfQAhIAqWKYnSflMBvrC4Cxu
Product

nanoporous trinuclear copper pyrazolate-based metal-organic framework

Pore width: ~ 1 - 3.5 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • zinc nitrate hexahydrate
  • copper(II) nitrate trihydrate
  • 4-pyrazolecarboxylic acid
  1. u0G8SIYiaTtlTExLAyLDCkFQzxv3YEplIWCLsaX61zaIn54U1QL6J
Product

nanoporous trinuclear copper pyrazolate-based metal-organic framework

Pore width: ~ 1 - 3.5 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • zinc nitrate hexahydrate
  • copper(II) nitrate trihydrate
  • 4-pyrazolecarboxylic acid
  1. n096LVO2Qhe1Mo0DahyzAShPYdUWRUu2DIdEQuCKgmroyODfyUKq0
Product

nanoporous trinuclear copper pyrazolate-based metal-organic framework

Pore width: ~ 1 - 3.5 nm

Medium/Support: none

References

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