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carboxylic moieties-modified metal-organic framework consisting zinc-carboxylate clusters bridged by two different organic ligands

Based on

1 Articles
2017 Most recent source

Composition

1

zinc(II) cation

zinc dication zinc(2+) ion zinc(II) ion zinc cation Zn2+ ion zinc ion zinc(2+) zinc(II) Zn ion Zn(2+) Zn2+
Type Single Compound
Formula Zn2+
Role framework element
2

4,4',4''-benzene-1,3,5-triyl-tribenzoic acid

4,4',4''-benzene-1,3,5-triyltribenzoic acid 1,3,5-tris(4-carboxyphenyl)benzene 1,3,5-benzenetribenzoic acid BTBH3 H3BTB H3btb TCPB BTB
Type Single Compound
Formula C27H18O6
Role framework element
3

2-amino-1,4-benzene dicarboxylic acid

2-amino-1,4-benzenedicarboxylic acid 2-aminobenzene-1,4-dicarboxylic acid 2-amino-1,4-benzenecarboxylic acid 2-amino-1,4-dicarboxylic acid 2-amino-1,4-dicarboxybenzene 2-amino terephthalic acid 2-amino-terephthalic acid 2-aminoterephthalic acid aminoterephthalic acid H2N-BDC-NH2 H2BDC(NH2) NH2-H2 BDC H2BDC-NH2 NH2-BDCH2 NH2-H2BDC BDC-NH2 NH2-BDC BDC-NH2 H2N-BDC NH2-BDC NH2-bdc bdc-NH2 NH2BDC H2ATA abdc
Type Single Compound
Formula C8H7NO4
Role framework element
4

4-hydroxy-4-oxo-butanoyl group

succinic acid anhydride moiety 4-hydroxy-4-oxobutanoyl group succinic anhydride moiety 3-carboxypropanoyl group succinic acid moiety carboxyl terminal succinyl group SA moiety
Type Single Compound
Formula -C4H5O3
Role layer

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
Nitrogen adsorption/desorption

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Characterization

Method Nanomaterial Variant Source
infrared spectroscopy

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • zinc nitrate hexahydrate
  • 2-amino-1,4-benzene dicarboxylic acid
  • 4,4',4''-benzene-1,3,5-triyl-tribenzoic acid
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Product

carboxylic moieties-modified metal-organic framework consisting zinc-carboxylate clusters bridged by two different organic ligands

Pore size: ~ 1.7 nm

Medium/Support: none

References

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