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peroxo-hydroxo-hafnium clusters

Based on

20 Articles
2018 Most recent source

Composition

1

Hf6(μ-O2)6(μ-OH)6(OH)12

Type Single Compound
Formula Hf6(O2)6(OH)18
Role framework element
2

tetramethylammonium hydroxide ion

tetramethylammonium cation tetramethylammonium ion tetramethylammonium TMAOH ion TMA ion TMA+ TMA
Type Single Compound
Formula C4H12N
Role framework element
3

water

Type Single Compound
Formula H2O
Role framework element

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
capped-uncapped form relative energy

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Sensor properties

Type of sensor Sensor property Nanomaterial Variant Source
compounds sensor for ATP in serum

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Applications

Area Application Nanomaterial Variant Source
catalysis

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Characterization

Method Nanomaterial Variant Source
mass spectrometry

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nuclear magnetic resonance spectroscopy
UV
UV-Vis spectroscopy

Biological effects

Biological system Test details Nanomaterial Variant Source
143B cells

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • 2,2-difluoro-4,6,10,12-tetramethyl-8-(4-methylphenyl)-5,11-bis(pyridin-4-yl)-1λ4,3-diaza-2λ4-boratricyclo[7.3.0.03,7]dodeca-1(12),4,6,8,10-pentaene
  • tetrasodium 4-(4-{tris[4-(4-carboxylatophenyl)phenyl]ethenyl}phenyl)benzoate
  • bis(triethyl-λ4-phosphanyl)(trifluoromethanesulfonyloxy)platinio trifluoromethanesulfonate
  1. DFVWn0YxsNVw5jzswNuTbwOVloV9EtP8cFrMIY0z161
Product

peroxo-hydroxo-hafnium clusters

Diameter: 3.8 nm

Height: 1.94 nm

Length: ~ 2 nm

Width: 1.75 nm

Medium/Support: none

Method 2

Type: Physical formation
Source:
Starting materials
  1. AH95gouXSaQeysAqsM3wFv3II
  2. 336nPJn4ymXaArJM
  3. md4
  4. gXcuhvT8
  5. D8SzKhdX
Product

peroxo-hydroxo-hafnium clusters

Size: not specified

Medium/Support: none

Method 3

Type: Physical formation
Source:
Starting materials
  1. vSZal3iyTD59p9IEmfIa4xHjM
  2. d6QAiCIw0hEaoxXQ
  3. P4f
  4. FwVnjCoz
  5. Ssq7CsxN
Product

peroxo-hydroxo-hafnium clusters

Arm length: ~ 4.5 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • calcium(II) chloride
  • Dulbecco's modified Eagle medium
  1. iDLr6OR6x6rArx
  2. FLFmL
Product

peroxo-hydroxo-hafnium clusters

Size: 40 - 50 nm

Medium/Support: none

Method 5

Type: Physical formation
Source:
Starting materials
  1. Wbzbmk8x9UiAaOtvHMahlDkUE
  2. 9vOQObaP21uqCEWP
  3. gRS
  4. tcft9PiH
  5. Id5KHEMv
Product

peroxo-hydroxo-hafnium clusters

Size: not specified

Medium/Support: none

References

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