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7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole):PC61BM:poly(methyl methacrylate) blend film

Based on

1 Articles
2016 Most recent source

Composition

1

7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole)

7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzothiadiazole) p-DTG(FBTTh2)2 DTGe(FBTTh2)2
Type Single Compound
Formula C64H72F2GeN4S8
Role raw materials
2

methanofullerene phenyl C61 butyric acid methyl ester

[6,6]-phenyl C61 butyric acid methyl ester fullerene [6,6]-phenyl-C61-butyric acid methyl ester fullerene [6,6]-phenyl-C61-butyric acid methyl ester particles [6,6]-phenyl-C61-butyric acid methyl ester fullerene [6,6]-phenyl C61 butyric acid methyl ester molecule 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6) C61 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C60 [6,6]-phenyl-C 60 -butyric acid methyl ester [6,6]-phenyl-C61-butyric acid methyl ester [6,6]-phenyl-C61-butyric acid methyl ester (6,6)-phenyl C61 butyric acid methyl ester [6,6]-phenyl C61-butyric acid methyl ester [6,6]-phenyl C61-acid butyric-methyl ester (6,6)-phenyl-C61-butyric acid methyl ester (6,6)-phenyl C61 butyric acid methyl ester [6,6]-phenyl-C61 butyric acid methyl ester [6,6]-phenyl-C60-butyric acid methyl ester [6,6]- phenyl C61-butyric acid methylester [6,6]-phenyl-C61 butyric acid methyl ester (6,6)-phenyl C61-butyric acid methyl ester [6,6]-phenyl C61-butyric acid methyl ester [6,6]-phenyl C61 butyric acid methyl ester [6,6]-phenyl C61 butyric acid methyl ester [6,6]-phenylC61 butyric acid methyl ester [6,6]-phenyl-C61-butyl acid methyl ester 6,6-phenyl-C61-butyric acid methyl ester [6]-phenyl-C61-butyric acid methyl ester phenyl-C61-butyric acid methyl ester phenyl C61 acid butyric-methyl ester [6,6]-phenyl C61 butyric acid methyl phenyl-C60-butyric acid methyl ester phenyl-C61-butyric acid methyl ester phenyl-C60-butyric acid methyl ester phenyl-C61 butyric acid methyl ester [6,6]-phenyl-C61-butyric acid ester phenyl-C61-butyrate methyl ester C61-butyric acid methyl ester carbon nanoparticles of PCBM [6,6]-phenyl C61-butyric PCBM fullerene particles PC61BM fullerene PC61BM fullerene PC60BM fullerene PCBM fullerenes PCBM fullerene mono-PC61BM mono-PCBM PC[60]BM [60]PCBM C61PCBM PC661BM PC61BM PC60BM PC61BM PC60BM mPCBM PCBM PCMB
Type Nano Material
Formula
Role raw materials
3

polystyrene

PS
Type Polymer
Formula
Role dopant

Applications

Area Application Nanomaterial Variant Source
power generation

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Characterization

Method Nanomaterial Variant Source
atomic force microscopy

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Preparation

Method 1

Type: Physical formation
Source:
Starting materials
  • poly(dimethylsiloxane)
  • [6,6]-phenyl-C61-butyric acid methyl ester
  • 7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole)
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Product

7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole):PC61BM:poly(methyl methacrylate) blend film

Crystallite correlation length: ~ 22 nm

RMS roughness: 0.731 nm

Medium/Support: none

Method 2

Type: Physical formation
Source:
Starting materials
  • [6,6]-phenyl-C61-butyric acid methyl ester
  • polystyrene
  • 7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole)
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Product

7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole):PC61BM:poly(methyl methacrylate) blend film

Crystallite correlation length: ~ 21 nm

RMS roughness: 0.778 nm

Medium/Support: none

Method 3

Type: Physical formation
Source:
Starting materials
  • [6,6]-phenyl-C61-butyric acid methyl ester
  • poly(methyl methacrylate)
  • 7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole)
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Product

7,7'-(4,4-bis(2-ethylhexyl)-4H-germolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole):PC61BM:poly(methyl methacrylate) blend film

Crystalline domain length: 20 - 40 nm

Crystalline domain width: 7 - 13 nm

Crystallite correlation length: ~ 22 nm

RMS roughness: 1.020 nm

Medium/Support: none

References

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