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[Pd6{2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12 metallosupramolecular spheres

Based on

1 Articles
2014 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

[Pd6{(M)-2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12

[Pd6{(P)-2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12
Type Single Compound
Formula C408H336B12F48N24O48Pd6
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
diffusion coefficient

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Characterization

Method Nanomaterial Variant Source
circular dichroism

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Preparation

Method 1

Type: Physical formation
Source:
Product

[Pd6{2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12 metallosupramolecular spheres

Hydrodynamic diameter: ~ 2 - ~ 8 nm

Radius: 1.05 - 1.62 nm

Medium: acetonitrile

Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • deuterated acetonitrile
  • 2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl
  1. uWY
  2. N7VNf
Product

[Pd6{2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12 metallosupramolecular spheres

Hydrodynamic radius: 1.30 nm

Radius: 1.05 - 1.62 nm

Medium: deuterated acetonitrile

Support: none

Method 3

Type: Physical formation
Source:
  1. 22K9fBUNnKXcELzeeVLFX0ULLgv986MttRch2zwlAVZ
Product

[Pd6{2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12 metallosupramolecular spheres

Particle size: ~ 3 nm

Radius: 1.05 - 1.62 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • dimethylsulfoxide-d6
  • 2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl
  1. bxd
  2. LNBYc
Product

[Pd6{2,2'-di(methoxymethoxy)-3,3'-di(4-pyridyl)-1,1'-binaphthyl}12](BF4)12 metallosupramolecular spheres

Hydrodynamic radius: 1.51 nm

Radius: 1.05 - 1.62 nm

Medium: dimethylsulfoxide-d6

Support: none

References

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