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2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Based on

1 Patents
2010 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

1-butyl-3-methylimidazolium hexafluorophosphate

BMIM-PF6
Type Single Compound
Formula C8H15F6N2P
Role binder
2

2,2'-bipyridine-stabilized rhodium nanoparticles

2,2'-bipyridine-stabilized Rh nanoparticles
Type Nano Material
Formula
Role fillers

Properties

Catalytic properties

Reaction Value Nanomaterial Variant Source
Hydrogenation

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Applications

Area Application Nanomaterial Variant Source
catalysis

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • n-methyl-(n-butyl) pyrrolidinium bis(trifluoromethanesulfonyl)imide
  • rhodium(III) chloride trihydrate
  1. fY2r7XAMH1OxR9jCNIJaPi2ccf
  2. V1gsqiH23DXslFNPWfz2k35fVxdCFJwTV3Bv
  3. 94ED9Q24ej0ehA2W
Product

2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Size: not specified

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • N,N'-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide
  • rhodium(III) chloride trihydrate
  1. o4LoTU6GpCtDW35wUh8U3OXKAG
  2. 6cMyw7BrAu6lR01cDtRjIShlKae8PPEGJfI9
  3. Af3O0pEzRSq3ymaT
Product

2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Size: not specified

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • 1-n-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide
  • rhodium(III) chloride trihydrate
  1. VlwmZqDq9SKOLhe04uCMquXrpu
  2. KYmzahxxFkfteH84a6C74nuUH6CwGXu23c1R
  3. vZVleHHjZYaha4cB
Product

2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Size: not specified

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • 1-butyl-3-methylimidazolium tetrafluoroborate
  • rhodium(III) chloride trihydrate
  1. Y2nBd2u8gIzLs6z5PWBlUYaFD2
  2. I6Nxn2tnEtgAmWwZmR7ooLI86Wb3q2RFoPQP
  3. zzUlSPyeYJsPD4Fo
Product

2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Size: not specified

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • 1-butyl-3-methylimidazolium hexafluorophosphate
  • rhodium(III) chloride trihydrate
  1. GAKj6zxUJwWNNsNIMsjFI9tWEf
  2. GRga2YZtTWMsXMpkqa9O0d2M8qvhknaOrPPz
  3. QtxraKqD0VWKXrDz
Product

2,2'-bipyridine-stabilized rhodium nanoparticles in N,N-dimethyl-N-dodecyl-N-(hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)amide

Size: not specified

Medium/Support: none

References

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