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CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Based on

5 Articles
2018 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

Zr-BTC metal-organic framework

Zr-BTC MOF MOF-808
Type Complex Compound
Formula
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
hydrogen adsorption isosteric heat

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Catalytic properties

Reaction Value Nanomaterial Variant Source
1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene hydrogenation

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Applications

Area Application Nanomaterial Variant Source
catalysis

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Characterization

Method Nanomaterial Variant Source
extended X-ray absorption fine structure

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Preparation

Method 1

Type: Chemical synthesis
Source:
  1. n3uGXYY9HgeW2sOkPdnnWX0KZH2hLs
  2. sHLwB
Product

CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Pore diameter: 0.8 - 9.0 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • dodecanoic acid
  • zirconium tetrachloride
  1. 3W3
Product

CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Pore size: ~ 1 - ~ 5.8 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • 1,3,5-benzene tricarboxylic acid
  • zirconium dichloride oxide octahydrate
  1. ze3
  2. 8H39a
Product

CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Pore size: 2.3 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • dodecanoic acid
  • zirconium tetrachloride
  1. wD5
Product

CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Pore size: ~ 4.3 nm

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
  1. kDUSz
  2. QJqwC8uiE0BIHDyFPTyZhLftXZNJAY9x5hKbRe9z
Product

CoCl-metalated Zr-4',4''',4''''',4''''''-methanetetrayltetrakis([1,1'-biphenyl]-4-carboxylic acid) metal-organic framework

Pore diameter: ~ 1.6 - ~ 1.8 nm

Medium/Support: none

References

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