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mesoporous supramolecular framework

Based on

14 Articles
2018 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

L-proline functionalized zirconium based metal-organic framework

Zr6O4(OH)4(bpdc-NHPro)5.5(benz)2.5(H2O)7.5(EtOH)2.5 L-proline functionalized zirconium based MOF proline functionalized UiO-67 UiO-67-NHPro
Type Complex Compound
Formula
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
Nitrogen adsorption/desorption

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Surface area

Catalytic properties

Reaction Value Nanomaterial Variant Source
aldol addition of cyclohexanone and 4-nitrobenzaldehyde

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Applications

Area Application Nanomaterial Variant Source
adsorbents/absorbers/ion exchange materials

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Characterization

Method Nanomaterial Variant Source
infrared spectroscopy

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nuclear magnetic resonance spectroscopy
thermogravimetric analysis
X-ray diffraction

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • uranyl nitrate hexahydrate
  • 5'-(4-carboxyphenyl)-2',4',6'-trimethyl-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid
  • N,N'-dimethylformamide
  1. GmO1ZQgb8AjsIqGJejns
  2. 7Bh2co
  3. EKHdB
Product

mesoporous supramolecular framework

Pore size: 12 - 70 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • copper(II) nitrate hexahydrate
  • nitric acid
  • N,N'-dimethylformamide
See all (4)
  1. 62Wj4Ji5E1SWs9nSyz1
Product

mesoporous supramolecular framework

Pore size: 0.695 - 1.396 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • benzoic acid
  • zirconium tetrachloride
  1. lvrM8Tz
Product

mesoporous supramolecular framework

Pore diameter: ~ 0.88 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • calcium(II) chloride
  • (Me4N)2{Cu2[(S,S)-alamox](OH)26H2O
  1. 9AIDrxyl0M3qDSsO
Product

mesoporous supramolecular framework

Pore size: 1.1 nm

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • azobenzene-4,4'-dicarboxylate
  • metal-organic framework
  1. bfgv383fv3I3BX
  2. FvonM
  3. FwsOW5
Product

mesoporous supramolecular framework

Pore diameter: > 2 nm

Medium/Support: none

References

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