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mesoporous supramolecular framework

Based on

14 Articles
2018 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

gradient metal-organic framework

bMOF-102/106
Type Complex Compound
Formula
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
nitrogen adsorption/desorption

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surface area

Catalytic properties

Reaction Value Nanomaterial Variant Source
aldol addition of cyclohexanone and 4-nitrobenzaldehyde

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Applications

Area Application Nanomaterial Variant Source
adsorbents/absorbers/ion exchange materials

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Characterization

Method Nanomaterial Variant Source
infrared spectroscopy

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nuclear magnetic resonance spectroscopy
thermogravimetric analysis
X-ray diffraction

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • uranyl nitrate hexahydrate
  • N,N'-dimethylformamide
  • 5'-(4-carboxyphenyl)-2',4',6'-trimethyl-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid
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Product

mesoporous supramolecular framework

Pore size: 12 - 70 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
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Product

mesoporous supramolecular framework

Pore diameter: > 2 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • copper(II) nitrate hexahydrate
  • nitric acid
  • N,N'-dimethylformamide
See all (4)
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Product

mesoporous supramolecular framework

Pore size: 0.695 - 1.396 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • titanium(IV) tetraethoxide
  • water
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  3. oW0wcM
Product

mesoporous supramolecular framework

Pore-pore separation: 2 nm

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • 2,2'-bis-(4-hydroxyphenyl)propane
  • titanium(IV) tetraethoxide
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Product

mesoporous supramolecular framework

Pore-pore separation: 2 nm

Medium/Support: none

References

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