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modified Binol-periodic mesoporous organosilica SBA-15 type material

Based on

1 Articles
2013 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

silicon dioxide

silicic oxide silica
Type Single Compound
Formula SiO2
Role raw materials
2

bis-silylated chiral Binol derivative moiety

Type Single Compound
Formula -C30H30N2O4Si2-
Role graft

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
Nitrogen adsorption/desorption

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Catalytic properties

Reaction Value Nanomaterial Variant Source
thioanisole asymmetric oxidation

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Applications

Area Application Nanomaterial Variant Source
catalysis

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Characterization

Method Nanomaterial Variant Source
nuclear magnetic resonance spectroscopy

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • silicic acid tetraethyl ester
  1. YkUUqVm7KxdFbcuBKfioFiXONT97y7nA2S8bMtwkZizBTF7
  2. v9e60
  3. kPpiaYvyqHkrg8flg
  4. 69S37
Product

modified Binol-periodic mesoporous organosilica SBA-15 type material

Pore diameter: ~ 5.61 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • silicic acid tetraethyl ester
  1. USwuszvcSII7dYlWNO4wR0RAVlTS0P0UBTN1oU2K3hRkbqB
  2. g9G
  3. 2CMtNBpcVXjzLN3ld
  4. 5iqyl
Product

modified Binol-periodic mesoporous organosilica SBA-15 type material

Pore diameter: ~ 5.41 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • silicic acid tetraethyl ester
  1. BJsyN0U8re8Srk8hM3Kr4pKi4MJUirLkiHzbWAIMoEf6p8L
  2. gYR
  3. pwQFrY8ho1Smbto2T
  4. AaOXr
Product

modified Binol-periodic mesoporous organosilica SBA-15 type material

Pore diameter: ~ 5.82 nm

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • silicic acid tetraethyl ester
  1. lbZydHCHN2Flvlexm3PRwvqnxFqnnqLYnANWlbEFiN5gqeD
  2. y2I
  3. 1NzFORbS9oinQFeiJ
  4. iX57s
Product

modified Binol-periodic mesoporous organosilica SBA-15 type material

Size: not specified

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • silicic acid tetraethyl ester
  1. 4NiTdiIklHhaeaHCbv4niZgvalGlsnjdzKQxoLb4gUCi5iZ
  2. jMa
  3. YWFCv5ScqPsNA94ZP
  4. r4RYh
Product

modified Binol-periodic mesoporous organosilica SBA-15 type material

Pore diameter: ~ 6.45 nm

Medium/Support: none

References

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