Loading ...

Zr-based metal-organic framework nanocrystals

Based on

7 Articles
2018 Most recent source

Composition

1

zirconium-oxy-hydroxy unit

zirconium cluster Zr6 cluster
Type Single Compound
Formula [Zr6O4(OH)4](12+)
Role framework element
2

biphenyl-4,4'-dicarboxylic acid dianion

4-(4-carboxylatophenyl)benzoate 4,4'-biphenyldicarboxylic acid biphenyl- 4,4'-dicarboxylate biphenyl-4,4'-dicarboxylate 4,4'-biphenyldicarboxylate bpdc2- BPDC
Type Single Compound
Formula C14H8O4
Role framework element

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
compressive load dependent on load change direction

More information/entries available to subscribers only.

Or, view sample content

Catalytic properties

Reaction Value Nanomaterial Variant Source
phenyl sulfide oxidation to diphenyl sulfone

More information available to subscribers only.

Or, view sample content

Applications

Area Application Nanomaterial Variant Source
adsorbents/absorbers/ion exchange materials

More information/entries available to subscribers only.

Or, view sample content

Characterization

Method Nanomaterial Variant Source
X-ray diffraction

More information/entries available to subscribers only.

Or, view sample content

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • zirconium dichloride oxide octahydrate
  • trans-azobenzene-4,4'-dicarboxylic acid
  1. LLXphSH824e
  2. Dosgfy5ZB2TffSHubwMRI
  3. dOCUE
Product

Zr-based metal-organic framework nanocrystals

Size: ~ 500 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • water
  • biphenyl- 4,4'-dicarboxylic acid
See all (4)
  1. 6N6a3klHGKhWLRY5U
  2. oTixm
  3. KJ9Lkc
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • biphenyl- 4,4'-dicarboxylic acid
  • zirconium tetrachloride
  1. mEybXpNQU4E5cmtMO
  2. idCFG
  3. Cz6S
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • fumaric acid
  • zirconium tetrachloride
  1. Wx3hcZmH2pX
  2. 1KyH5ci0FV67kMBcnJqja
  3. WBAV4
Product

Zr-based metal-organic framework nanocrystals

Size: ~ 300 nm

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • hafnium tetrachloride
  • 2-amino-1,4-benzene dicarboxylic acid
See all (4)
  1. zpbsTXDSBpg0jaaAM
  2. DmOpb
  3. aXz3TL
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

References

Full content is available to subscribers only

To view content please choose from the following:


Sign up for a free trial