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Zr-based metal-organic framework nanocrystals

Based on

7 Articles
2018 Most recent source

Composition

1

zirconium cluster

Type Single Compound
Formula [Zr6(OH)8](16+)
Role framework element
2

tetrakis(4-carboxyphenyl)porphyrin nickel anion

Ni-TCPP anion
Type Single Compound
Formula C49H27N4NiO8
Role framework element

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
compressive load dependent on load change direction

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Catalytic properties

Reaction Value Nanomaterial Variant Source
phenyl sulfide oxidation to diphenyl sulfone

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Applications

Area Application Nanomaterial Variant Source
adsorbents/absorbers/ion exchange materials

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Characterization

Method Nanomaterial Variant Source
X-ray diffraction

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Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • zirconium dichloride oxide octahydrate
  • trans-azobenzene-4,4'-dicarboxylic acid
  1. ZvuSDkm8NqZ
  2. m1ZrMpp4XfBUbtvrrjVsE
  3. KUfG6
Product

Zr-based metal-organic framework nanocrystals

Size: ~ 500 nm

Medium/Support: none

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • water
  • biphenyl- 4,4'-dicarboxylic acid
See all (4)
  1. pXgh5jlftPQ1dgFye
  2. Ma1Wa
  3. FUkfME
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • biphenyl- 4,4'-dicarboxylic acid
  • zirconium tetrachloride
  1. G4t8oByiBsjo9dvzy
  2. pDWI2
  3. XJp3
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

Method 4

Type: Chemical synthesis
Source:
Starting materials
  • fumaric acid
  • zirconium tetrachloride
  1. 1sZMj0P1GLp
  2. 2kXjPhet54OfYmAAOnaXn
  3. rT7UT
Product

Zr-based metal-organic framework nanocrystals

Size: ~ 300 nm

Medium/Support: none

Method 5

Type: Chemical synthesis
Source:
Starting materials
  • methanecarboxylic acid
  • hafnium tetrachloride
  • 2-amino-1,4-benzene dicarboxylic acid
See all (4)
  1. yK3skRRHeVrLR6oNn
  2. dp82Q
  3. KrZTiP
Product

Zr-based metal-organic framework nanocrystals

Size: not specified

Medium/Support: none

References

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