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(Mn1.77Ni1.23O)2(TCPP-Ni)3 multivariate metal-organic framework

Based on

1 Articles
2016 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

Mn1.77Ni1.23O secondary building unit

Mn1.77Ni1.23O SBU
Type Complex Compound
Formula
Role framework element
2

[5,10,15,20-tetrakis(4- methoxycarbonylphenyl)porphyrinato]-Ni(II)

nickel(II) tetrakis(4-carboxyphenyl)porphyrin tetrakis(4-carboxyphenyl)porphyrin-nickel(II) Ni-TCPP TCPP-Ni NiTCPP
Type Single Compound
Formula C48H28N4NiO8
Role framework element

Properties

General physical and chemical properties

Property Value Source
Nitrogen adsorption/desorption

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Catalytic properties

Reaction Value Source
1,5-dihydroxynaphthalene photooxidation

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Applications

Area Application Source
catalysis

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Characterization

Method Source
X-ray absorption near edge fine structure spectroscopy

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Biological effects

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • [5,10,15,20-tetrakis(4- methoxycarbonylphenyl)porphyrinato]-Ni(II)
  • nickel(II) nitrate hexahydrate
  • manganese(II) chloride tetrahydrate
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Product

(Mn1.77Ni1.23O)2(TCPP-Ni)3 multivariate metal-organic framework

References

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