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CeO2-supported [Au25(SC6H13)18]-[TOA]+ nanoclusters

Based on

1 Articles
2016 Most recent source

Composition

1

gold

Type Single Compound
Formula Au
Role core
2

1-mercaptohexane moiety

hexanethiolate moiety 1-hexanethiol moiety hexanethiol moiety hexan-1-thiolate n-hexanthiolate hexanethiolate MCH moiety CH3-C5-S- C6-S- SC6
Type Single Compound
Formula -C6H13S
Role layer
3

tetra(n-octyl)ammonium cation

tetraoctylammonium cation tetra(n-octyl)ammonium tetraoctylammonium ion tetraoctylammoniun+ tetraoctylammonium TOA+ TOA
Type Single Compound
Formula C32H68N
Role raw materials

Properties

Catalytic properties

Reaction Value Source
Ullmann heterocoupling between 4-methyliodobenzene and 4-nitroiodobenzene

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Applications

Area Application Source
catalysis

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Characterization

Method Source
UV-Vis-NIR optical spectroscopy

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Biological effects

Preparation

Method 1

Type: Physical formation
Source:
Starting materials
  1. XjY6wb37LDTuCuY
Product

CeO2-supported [Au25(SC6H13)18]-[TOA]+ nanoclusters

Method 2

Type: Chemical synthesis
Source:
Starting materials
  • gold trichloride hydrochloride trihydrate
  • tetra(n-octyl)ammonium bromide
  • 1-mercaptohexane
  1. wrIDYXC6QAGQP5Z
Product

CeO2-supported [Au25(SC6H13)18]-[TOA]+ nanoclusters

References

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