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7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

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1 Articles
2016 Most recent source

Composition

1

4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole

((7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5- b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole))) 7,7';-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b';]-dithiophene-2,6-diyl)bis(6-fluoro-4-(5';-hexyl-[2,2';-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole 7,7-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene- 2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)- benzo[c][1,2,5] thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']-dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)-benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']-dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophene]-5-yl)benzo[c] [1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'- bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b.]dithiophene-2,6-diyl) bis(6-fluoro-4-(5'-hexyl-[2,2.-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo-[c] [1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-5-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazaole) 7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole] 7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole] 7,7-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2- b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5yl)-benzo[c][1,2,5]thiadiazole 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5';-hexyl[2,2'bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) p-DTSi(FBTTh2)2 p-DTS(FBTTH2)2 p-DTS(FBTTH2)2 p-DTS(FBTTh2)2 DTSi(FBTTh2)2 DTS(FBTTh2)2 DTS-F F-DTS T1
Type Single Compound
Formula C64H72F2N4S8Si
Role raw materials
2

3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester

(6,6)-phenyl-C71-butyric acid methyl ester [6,6]-phenyl C71 butyric acid methyl ester [6,6]-phenyl-C71-butyric acid methyl ester [70]PCBM PC71BM PC71BM
Type Single Compound
Formula C82H14O2
Role raw materials

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
electron mobility

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Applications

Area Application Nanomaterial Variant Source
power generation

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Characterization

Method Nanomaterial Variant Source
atomic force microscopy

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Biological effects

Preparation

Method 1

Type: Physical formation
Source:
Starting materials
  • 4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole
  • 3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester
  1. o029jLYuVOMQ0Pm6Qxeq6lTLhR1O9aHJh79Mjr0
Product

7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

Crystal correlation length: 4.8 - 10.3 nm

Medium/Support: none

Method 2

Type: Physical formation
Source:
Starting materials
  • 4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole
  • 3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester
  1. eLUMaFcTPiPSOMYW0heysPBzfWH2U153tiDLlH6
Product

7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

Crystal correlation length: ~ 13 - ~ 16 nm

Medium/Support: none

Method 3

Type: Physical formation
Source:
Starting materials
  • 4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole
  • 3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester
  1. rwP4KT0XW5zbtiSex2vbq90DNTESXkCx0BdQsaT
Product

7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

Crystal correlation length: ~ 12 - ~ 14 nm

Medium/Support: none

Method 4

Type: Physical formation
Source:
Starting materials
  • 4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole
  • 3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester
  1. ZjkpdKhBT3n9x0UvmIBB8jitrMuDjENvYJ7TQ10
Product

7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

Crystal correlation length: ~ 12 - ~ 14 nm

Medium/Support: none

Method 5

Type: Physical formation
Source:
Starting materials
  • 4-[7,7-bis(2-ethylhexyl)-10-{5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazol-4-yl}-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraen-4-yl]-5-fluoro-7-[5-(5-hexylthiophen-2-yl)thiophen-2-yl]-2,1,3-benzothiadiazole
  • 3'-phenyl-3'H-cyclopropa[8,25][5,6]fullerene-C70-D5h(6)-3'-butanoic acid, methyl ester
  1. 6GKU2m3Q1sUp0cRRHGFElVFQQYlylJEO5RGnhX2
Product

7,7'-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl]bis[6-fluoro-4-(5'-hexyl[2,2'-bithiophene]-5-yl)benzo[c][1,2,5]thiadiazole]:phenyl C71 butyric acid methyl ester blend film

Crystal correlation length: ~ 6 - 14 nm

Medium/Support: none

References

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