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[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Based on

2 Articles
2016 Most recent source

Composition

1

[Pd12{1,3-di(pyridin-4-yl)benzene}24]24+ polyhedron

Type Nano Material
Formula
Role core
2

tetrafluoroborate anion

tetrafluoroborate ion tetrafluoroboranuide tetrafluoroborate BF4 anion
Type Single Compound
Formula BF41-
Role layer

Properties

General physical and chemical properties

Property Value Nanomaterial Variant Source
diffusion coefficient

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Applications

Characterization

Method Nanomaterial Variant Source
atomic force microscopy

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Biological effects

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • pyridine-capped banana-shaped bidentate ligand
  • dimethylsulfoxide-d6
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Diameter: 3.5 nm

Hydrodynamic radius: 1.80 nm

Medium: dimethylsulfoxide-d6

Support: none

Method 2

Type: Physical formation
Source:
  1. QLp6AXyTi8ILMTrKOxkw9uA7vMHpPTcLlg4jTTeBSlg
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Particle size: ~ 3 - ~ 5 nm

Medium/Support: none

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • 2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl
  • deuterated acetonitrile
  1. 9VV
  2. BUGaH
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Hydrodynamic radius: 2.76 nm

Medium: deuterated acetonitrile

Support: none

Method 4

Type: Physical formation
Source:
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Diameter: 3.5 nm

Hydrodynamic radius: ~ 2 - ~ 10 nm

Medium: dimethyl sulfoxide

Support: none

Method 5

Type: Physical formation
Source:
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Hydrodynamic diameter: ~ 3.5 - ~ 13 nm

Medium: acetonitrile

Support: none

References

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