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[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Based on

1 Articles
2014 Most recent source

Composition

Image only illustrates the order and placement of components as described in literature.

1

[Pd12{(P)-2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24]24+ polyhedron

[Pd12{(M)-2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24]24+ polyhedron
Type Nano Material
Formula
Role core
2

tetrafluoroborate anion

tetrafluoroborate ion tetrafluoroboranuide tetrafluoroborate BF4 anion
Type Single Compound
Formula BF41-
Role layer

Properties

General physical and chemical properties

Property Value Source
diffusion coefficient

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Applications

Characterization

Method Source
circular dichroism dependent on ligand chirality

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Biological effects

Preparation

Method 1

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • 2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl
  • deuterated acetonitrile
  1. zZb
  2. mW4I8
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Method 2

Type: Physical formation
Source:
  1. GzD46ouQqKvuy2X94Od0ORnR0s6B76R8pBIV5qg41zT
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

Method 3

Type: Chemical synthesis
Source:
Starting materials
  • tetrakis(acetonitrile)palladium(II) tetrafluoroborate
  • 2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl
  • dimethylsulfoxide
  1. bD0
  2. 76XTU
Product

[Pd12{2,2'-di(methoxymethoxy)-6,6'-di(4-pyridyl)-1,1'-binaphthyl}24](BF4)24 metallosupramolecular spheres

References

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